Contents

Section I Structures & Functions of Proteins & Enzymes

• Biochemistry & Medicine 1
• Water & pH 6
• Amino Acids & Peptides 15
• Proteins: Determination of Primary Structure 25
• Proteins: Higher Orders of Structure 36

Section II Enzymes: Kinetics, Mechanism, Regulation, & Bioinformatics

• Proteins: Myoglobin & Hemoglobin 51
• Enzymes: Mechanism of Action 60
• Enzymes: Kinetics 73
• Enzymes: Regulation of Activities 87
• Bioinformatics & Computational Biology 97

Section III Bioenergetics

• Bioenergetics: The Role of ATP
• Biologic Oxidation 119
• The Respiratory Chain & Oxidative Phosphorylation 126

Section IV Metabolism of Carbohydrates

• Overview of Metabolism & the Provision of Metabolic Fuels 139
• Carbohydrates of Physiological Significance 152
• The Citric Acid Cycle: The Central Pathway of Carbohydrate, Lipid & Amino Acid Metabolism 161
• Glycolysis & the Oxidation of Pyruvate 168
• Metabolism of Glycogen 176
• Gluconeogenesis & the Control of Blood Glucose 185
• Pathways of Hexose Metabolism 196

Section V Metabolism of Lipids

• Lipids of Physiologic Significance 211
• Oxidation of Fatty Acids: Ketogenesis 223
• Biosynthesis of Fatty Acids & Eicosanoids 232
• Metabolism of Acylglycerols & Sphingolipids 245
• Lipid Transport & Storage 253
• Cholesterol Synthesis, Transport, & Excretion 266

Section VI Metabolism of Proteins & Amino Acids

• Biosynthesis of the Nutritionally Nonessential Amino Acids 281
• Catabolism of Proteins & of Amino Acid Nitrogen 287
• Catabolism of the Carbon Skeletons of Amino Acids 297
• Conversion of Amino Acids to Specialized Products 313
• Porphyrins & Bile Pigments 323

Section VII Structure, Function, & Replication of Informational Macromolecules

• Nucleotides 339
• Metabolism of Purine & Pyrimidine
• Nucleotides 347
• Nucleic Acid Structure & Function 359
• DNA Organization, Replication, & Repair 370
• RNA Synthesis, Processing, & Modification 394
• Protein Synthesis & the Genetic Code 413
• Regulation of Gene Expression 428
• Molecular Genetics, Recombinant DNA, & Genomic Technology 451

Section VIII Biochemistry of Extracellular & Intracellular Communication

• Membranes: Structure & Function 477
• The Diversity of the Endocrine
• System 498
• Hormone Action & Signal
• Transduction 518

Section IX Special Topics (A)

• Nutrition, Digestion, & Absorption 537
• Micronutrients: Vitamins & Minerals 546
• Free Radicals & Antioxidant Nutrients 564
• Glycoproteins 569
• Metabolism of Xenobiotics 583
• Clinical Biochemistry 589

Section X Special Topics (B)

• Intracellular Traffic & Sorting of Proteins 607
• The Extracellular Matrix 627
• Muscle & the Cytoskeleton 647
• Plasma Proteins & Immunoglobulins 668
• Red Blood Cells 689
• White Blood Cells 700

Section XI Special Topics (C)

• 55 Hemostasis & Thrombosis 711
• 56 Cancer: An Overview 722
• 57 Biochemical Case Histories 746
• 58 The Biochemistry of Aging 755
• The Answer Bank 771
• Index 777

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